Please use this identifier to cite or link to this item: https://doi.org/10.1021/jacs.7b09417
Title: Mn(H2POO)3: A New Family of Hybrid Perovskites Based on the Hypophosphite Ligand
Authors: Wu, Y 
Shaker, S
Brivio, F
Murugavel, R
Bristowe, P.D
Cheetham, A.K 
Keywords: Functional materials
Perovskite
Single crystals
General formulas
Guanidinium
Imidazolium
Single-crystal diffraction
Structural distortions
Transition behavior
Manganese
guanidine derivative
hypophosphite
imidazole derivative
ligand
perovskite
phosphite
triazole derivative
unclassified drug
Article
crystal structure
density functional theory
hydrogen bond
phase transition
X ray powder diffraction
Issue Date: 2017
Publisher: American Chemical Society
Citation: Wu, Y, Shaker, S, Brivio, F, Murugavel, R, Bristowe, P.D, Cheetham, A.K (2017). Mn(H2POO)3: A New Family of Hybrid Perovskites Based on the Hypophosphite Ligand. Journal of the American Chemical Society 139 (47) : 16999-17002. ScholarBank@NUS Repository. https://doi.org/10.1021/jacs.7b09417
Rights: Attribution 4.0 International
Abstract: A family of five hybrid ABX3 perovskites has been synthesized using hypophosphite (H2POO)- as the X-site ion. These compounds adopt the general formula [Am]Mn(H2POO)3, where Am = guanidinium (GUA), formamidinium (FA), imidazolium, triazolium, and dabconium. We explore the diverse structural and phase transition behavior of these materials through single-crystal diffraction measurements and demonstrate contrasting magnetism in two of the phases, Am = GUA and FA, that arises from structural distortions. The results show that hypophosphite perovskites offer a promising platform for generating new functional materials. © 2017 American Chemical Society.
Source Title: Journal of the American Chemical Society
URI: https://scholarbank.nus.edu.sg/handle/10635/183853
ISSN: 0002-7863
DOI: 10.1021/jacs.7b09417
Rights: Attribution 4.0 International
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