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Please use this identifier to cite or link to this item: https://doi.org/10.1021/jacs.7b09417
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dc.titleMn(H2POO)3: A New Family of Hybrid Perovskites Based on the Hypophosphite Ligand
dc.contributor.authorWu, Y
dc.contributor.authorShaker, S
dc.contributor.authorBrivio, F
dc.contributor.authorMurugavel, R
dc.contributor.authorBristowe, P.D
dc.contributor.authorCheetham, A.K
dc.date.accessioned2020-11-23T08:50:14Z
dc.date.available2020-11-23T08:50:14Z
dc.date.issued2017
dc.identifier.citationWu, Y, Shaker, S, Brivio, F, Murugavel, R, Bristowe, P.D, Cheetham, A.K (2017). Mn(H2POO)3: A New Family of Hybrid Perovskites Based on the Hypophosphite Ligand. Journal of the American Chemical Society 139 (47) : 16999-17002. ScholarBank@NUS Repository. https://doi.org/10.1021/jacs.7b09417
dc.identifier.issn0002-7863
dc.identifier.urihttps://scholarbank.nus.edu.sg/handle/10635/183853
dc.description.abstractA family of five hybrid ABX3 perovskites has been synthesized using hypophosphite (H2POO)- as the X-site ion. These compounds adopt the general formula [Am]Mn(H2POO)3, where Am = guanidinium (GUA), formamidinium (FA), imidazolium, triazolium, and dabconium. We explore the diverse structural and phase transition behavior of these materials through single-crystal diffraction measurements and demonstrate contrasting magnetism in two of the phases, Am = GUA and FA, that arises from structural distortions. The results show that hypophosphite perovskites offer a promising platform for generating new functional materials. © 2017 American Chemical Society.
dc.publisherAmerican Chemical Society
dc.rightsAttribution 4.0 International
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.sourceUnpaywall 20201031
dc.subjectFunctional materials
dc.subjectPerovskite
dc.subjectSingle crystals
dc.subjectGeneral formulas
dc.subjectGuanidinium
dc.subjectImidazolium
dc.subjectSingle-crystal diffraction
dc.subjectStructural distortions
dc.subjectTransition behavior
dc.subjectManganese
dc.subjectguanidine derivative
dc.subjecthypophosphite
dc.subjectimidazole derivative
dc.subjectligand
dc.subjectperovskite
dc.subjectphosphite
dc.subjecttriazole derivative
dc.subjectunclassified drug
dc.subjectArticle
dc.subjectcrystal structure
dc.subjectdensity functional theory
dc.subjecthydrogen bond
dc.subjectphase transition
dc.subjectX ray powder diffraction
dc.typeArticle
dc.contributor.departmentMATERIALS SCIENCE AND ENGINEERING
dc.description.doi10.1021/jacs.7b09417
dc.description.sourcetitleJournal of the American Chemical Society
dc.description.volume139
dc.description.issue47
dc.description.page16999-17002
dc.published.statepublished
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