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|Title:||Reactions of bis(thiophosphoryl)disulfanes and bis(thiophosphinyl)disulfanes with metal species: An alternative, convenient route to metal complex and organometallic dithiophosphates and dithiophosphinates||Authors:||Haiduc, I.
Yoong Goh, L.
|Issue Date:||2002||Citation:||Haiduc, I.,Yoong Goh, L. (2002). Reactions of bis(thiophosphoryl)disulfanes and bis(thiophosphinyl)disulfanes with metal species: An alternative, convenient route to metal complex and organometallic dithiophosphates and dithiophosphinates. Coordination Chemistry Reviews 224 (1-2) : 151-170. ScholarBank@NUS Repository. https://doi.org/10.1016/S0010-8545(01)00402-7||Abstract:||The reactions of bis(thiophosphoryl)disulfanes, and bis(thiophosphinyl)disulfanes, X2P(S)SSP(S)X2 (X = R, OR; R = alkyl, aryl) with metals and low valent state metal compounds are reviewed. Four types of reactions of the disulfanes are possible: (a) adduct formation with ring closure through chelation (rare); (b) metal insertion, involving homolytic clevage of the S-S bond and oxidative addition of the metal species (typical for active metals and low valent metal species); (c) redistribution between M-M and S-S bonds, involving homolytic cleavage of both S-S and M-M bonds and oxidation of the metal with the formation of M-S bonds; (d) addition of the (S)PS-SP(S) moieties to metal-metal multiple bonds. © 2002 Elsevier Science B.V. All rights reserved.||Source Title:||Coordination Chemistry Reviews||URI:||http://scholarbank.nus.edu.sg/handle/10635/95572||ISSN:||00108545||DOI:||10.1016/S0010-8545(01)00402-7|
|Appears in Collections:||Staff Publications|
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