Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0010-8545(01)00402-7
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dc.titleReactions of bis(thiophosphoryl)disulfanes and bis(thiophosphinyl)disulfanes with metal species: An alternative, convenient route to metal complex and organometallic dithiophosphates and dithiophosphinates
dc.contributor.authorHaiduc, I.
dc.contributor.authorYoong Goh, L.
dc.date.accessioned2014-10-16T08:49:26Z
dc.date.available2014-10-16T08:49:26Z
dc.date.issued2002
dc.identifier.citationHaiduc, I.,Yoong Goh, L. (2002). Reactions of bis(thiophosphoryl)disulfanes and bis(thiophosphinyl)disulfanes with metal species: An alternative, convenient route to metal complex and organometallic dithiophosphates and dithiophosphinates. Coordination Chemistry Reviews 224 (1-2) : 151-170. ScholarBank@NUS Repository. <a href="https://doi.org/10.1016/S0010-8545(01)00402-7" target="_blank">https://doi.org/10.1016/S0010-8545(01)00402-7</a>
dc.identifier.issn00108545
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/95572
dc.description.abstractThe reactions of bis(thiophosphoryl)disulfanes, and bis(thiophosphinyl)disulfanes, X2P(S)SSP(S)X2 (X = R, OR; R = alkyl, aryl) with metals and low valent state metal compounds are reviewed. Four types of reactions of the disulfanes are possible: (a) adduct formation with ring closure through chelation (rare); (b) metal insertion, involving homolytic clevage of the S-S bond and oxidative addition of the metal species (typical for active metals and low valent metal species); (c) redistribution between M-M and S-S bonds, involving homolytic cleavage of both S-S and M-M bonds and oxidation of the metal with the formation of M-S bonds; (d) addition of the (S)PS-SP(S) moieties to metal-metal multiple bonds. © 2002 Elsevier Science B.V. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/S0010-8545(01)00402-7
dc.sourceScopus
dc.subjectBis(thiophosphinyl)disulfanes; Dithiophosphates
dc.subjectBis(thiophosphoryl)disulfanes
dc.subjectDithiophosphinates
dc.typeReview
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1016/S0010-8545(01)00402-7
dc.description.sourcetitleCoordination Chemistry Reviews
dc.description.volume224
dc.description.issue1-2
dc.description.page151-170
dc.description.codenCCHRA
dc.identifier.isiutNOT_IN_WOS
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