Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0010-8545(01)00402-7
Title: Reactions of bis(thiophosphoryl)disulfanes and bis(thiophosphinyl)disulfanes with metal species: An alternative, convenient route to metal complex and organometallic dithiophosphates and dithiophosphinates
Authors: Haiduc, I.
Yoong Goh, L. 
Keywords: Bis(thiophosphinyl)disulfanes; Dithiophosphates
Bis(thiophosphoryl)disulfanes
Dithiophosphinates
Issue Date: 2002
Citation: Haiduc, I.,Yoong Goh, L. (2002). Reactions of bis(thiophosphoryl)disulfanes and bis(thiophosphinyl)disulfanes with metal species: An alternative, convenient route to metal complex and organometallic dithiophosphates and dithiophosphinates. Coordination Chemistry Reviews 224 (1-2) : 151-170. ScholarBank@NUS Repository. https://doi.org/10.1016/S0010-8545(01)00402-7
Abstract: The reactions of bis(thiophosphoryl)disulfanes, and bis(thiophosphinyl)disulfanes, X2P(S)SSP(S)X2 (X = R, OR; R = alkyl, aryl) with metals and low valent state metal compounds are reviewed. Four types of reactions of the disulfanes are possible: (a) adduct formation with ring closure through chelation (rare); (b) metal insertion, involving homolytic clevage of the S-S bond and oxidative addition of the metal species (typical for active metals and low valent metal species); (c) redistribution between M-M and S-S bonds, involving homolytic cleavage of both S-S and M-M bonds and oxidation of the metal with the formation of M-S bonds; (d) addition of the (S)PS-SP(S) moieties to metal-metal multiple bonds. © 2002 Elsevier Science B.V. All rights reserved.
Source Title: Coordination Chemistry Reviews
URI: http://scholarbank.nus.edu.sg/handle/10635/95572
ISSN: 00108545
DOI: 10.1016/S0010-8545(01)00402-7
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