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https://doi.org/10.1016/j.jorganchem.2012.11.030
| Title: | The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water | Authors: | Lee, J.Y. Fan, W.Y. Mak, K.H.G. Leong, W.K. |
Keywords: | Aldehyde Iridium Photochemical activation Transition metal radical |
Issue Date: | 15-Jan-2013 | Citation: | Lee, J.Y., Fan, W.Y., Mak, K.H.G., Leong, W.K. (2013-01-15). The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water. Journal of Organometallic Chemistry 724 : 275-280. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2012.11.030 | Abstract: | The iridium complexes Cp*Ir(CO)(Cl)(CH2R), which do not contain any β-hydrogen atoms, react with water to form aldehydes. This reaction was found to be photochemically activated, and a possible pathway involving radical intermediates has been proposed and studied experimentally and computationally. © 2012 Elsevier B.V. All rights reserved. | Source Title: | Journal of Organometallic Chemistry | URI: | http://scholarbank.nus.edu.sg/handle/10635/95234 | ISSN: | 0022328X | DOI: | 10.1016/j.jorganchem.2012.11.030 |
| Appears in Collections: | Staff Publications |
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