The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water

Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2012.11.030

Title:	The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water
Authors:	Lee, J.Y. Fan, W.Y. Mak, K.H.G. Leong, W.K.
Keywords:	Aldehyde Iridium Photochemical activation Transition metal radical
Issue Date:	15-Jan-2013
Citation:	Lee, J.Y., Fan, W.Y., Mak, K.H.G., Leong, W.K. (2013-01-15). The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water. Journal of Organometallic Chemistry 724 : 275-280. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2012.11.030
Abstract:	The iridium complexes Cp*Ir(CO)(Cl)(CH2R), which do not contain any β-hydrogen atoms, react with water to form aldehydes. This reaction was found to be photochemically activated, and a possible pathway involving radical intermediates has been proposed and studied experimentally and computationally. © 2012 Elsevier B.V. All rights reserved.
Source Title:	Journal of Organometallic Chemistry
URI:	http://scholarbank.nus.edu.sg/handle/10635/95234
ISSN:	0022328X
DOI:	10.1016/j.jorganchem.2012.11.030
Appears in Collections:	Staff Publications

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