Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2012.11.030
Title: The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water
Authors: Lee, J.Y.
Fan, W.Y. 
Mak, K.H.G.
Leong, W.K.
Keywords: Aldehyde
Iridium
Photochemical activation
Transition metal radical
Issue Date: 15-Jan-2013
Citation: Lee, J.Y., Fan, W.Y., Mak, K.H.G., Leong, W.K. (2013-01-15). The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water. Journal of Organometallic Chemistry 724 : 275-280. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2012.11.030
Abstract: The iridium complexes Cp*Ir(CO)(Cl)(CH2R), which do not contain any β-hydrogen atoms, react with water to form aldehydes. This reaction was found to be photochemically activated, and a possible pathway involving radical intermediates has been proposed and studied experimentally and computationally. © 2012 Elsevier B.V. All rights reserved.
Source Title: Journal of Organometallic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/95234
ISSN: 0022328X
DOI: 10.1016/j.jorganchem.2012.11.030
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