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|Title:||The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water|
Transition metal radical
|Source:||Lee, J.Y., Fan, W.Y., Mak, K.H.G., Leong, W.K. (2013-01-15). The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water. Journal of Organometallic Chemistry 724 : 275-280. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2012.11.030|
|Abstract:||The iridium complexes Cp*Ir(CO)(Cl)(CH2R), which do not contain any β-hydrogen atoms, react with water to form aldehydes. This reaction was found to be photochemically activated, and a possible pathway involving radical intermediates has been proposed and studied experimentally and computationally. © 2012 Elsevier B.V. All rights reserved.|
|Source Title:||Journal of Organometallic Chemistry|
|Appears in Collections:||Staff Publications|
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