Template-directed synthesis of palladium(II) sulfonate-NHC complexes and catalytic studies in aqueous Mizoroki-Heck reactions

Please use this identifier to cite or link to this item: https://doi.org/10.1021/om500140g

Title:	Template-directed synthesis of palladium(II) sulfonate-NHC complexes and catalytic studies in aqueous Mizoroki-Heck reactions
Authors:	Yuan, D. Teng, Q. Huynh, H.V.
Issue Date:	14-Apr-2014
Citation:	Yuan, D., Teng, Q., Huynh, H.V. (2014-04-14). Template-directed synthesis of palladium(II) sulfonate-NHC complexes and catalytic studies in aqueous Mizoroki-Heck reactions. Organometallics 33 (7) : 1794-1800. ScholarBank@NUS Repository. https://doi.org/10.1021/om500140g
Abstract:	Oxidation of easily accessible thiolato-functionalized dinuclear Pd(II) NHC complexes 1-3 by Oxone gave rise to sulfonate-NHC complexes 4-6. This represents the first template-directed approach to NHC complexes bearing sulfonate functions, where the sulfur atoms undergo a six-electron oxidation, changing their oxidation states from -II to +IV. The catalytic activities of water-soluble 4-6 were also tested in aqueous Mizoroki-Heck reactions. © 2014 American Chemical Society.
Source Title:	Organometallics
URI:	http://scholarbank.nus.edu.sg/handle/10635/95201
ISSN:	15206041
DOI:	10.1021/om500140g
Appears in Collections:	Staff Publications

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