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|Title:||Template-directed synthesis of palladium(II) sulfonate-NHC complexes and catalytic studies in aqueous Mizoroki-Heck reactions|
|Citation:||Yuan, D., Teng, Q., Huynh, H.V. (2014-04-14). Template-directed synthesis of palladium(II) sulfonate-NHC complexes and catalytic studies in aqueous Mizoroki-Heck reactions. Organometallics 33 (7) : 1794-1800. ScholarBank@NUS Repository. https://doi.org/10.1021/om500140g|
|Abstract:||Oxidation of easily accessible thiolato-functionalized dinuclear Pd(II) NHC complexes 1-3 by Oxone gave rise to sulfonate-NHC complexes 4-6. This represents the first template-directed approach to NHC complexes bearing sulfonate functions, where the sulfur atoms undergo a six-electron oxidation, changing their oxidation states from -II to +IV. The catalytic activities of water-soluble 4-6 were also tested in aqueous Mizoroki-Heck reactions. © 2014 American Chemical Society.|
|Appears in Collections:||Staff Publications|
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