Please use this identifier to cite or link to this item: https://doi.org/10.1021/om500140g
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dc.titleTemplate-directed synthesis of palladium(II) sulfonate-NHC complexes and catalytic studies in aqueous Mizoroki-Heck reactions
dc.contributor.authorYuan, D.
dc.contributor.authorTeng, Q.
dc.contributor.authorHuynh, H.V.
dc.date.accessioned2014-10-16T08:45:01Z
dc.date.available2014-10-16T08:45:01Z
dc.date.issued2014-04-14
dc.identifier.citationYuan, D., Teng, Q., Huynh, H.V. (2014-04-14). Template-directed synthesis of palladium(II) sulfonate-NHC complexes and catalytic studies in aqueous Mizoroki-Heck reactions. Organometallics 33 (7) : 1794-1800. ScholarBank@NUS Repository. https://doi.org/10.1021/om500140g
dc.identifier.issn15206041
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/95201
dc.description.abstractOxidation of easily accessible thiolato-functionalized dinuclear Pd(II) NHC complexes 1-3 by Oxone gave rise to sulfonate-NHC complexes 4-6. This represents the first template-directed approach to NHC complexes bearing sulfonate functions, where the sulfur atoms undergo a six-electron oxidation, changing their oxidation states from -II to +IV. The catalytic activities of water-soluble 4-6 were also tested in aqueous Mizoroki-Heck reactions. © 2014 American Chemical Society.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1021/om500140g
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1021/om500140g
dc.description.sourcetitleOrganometallics
dc.description.volume33
dc.description.issue7
dc.description.page1794-1800
dc.description.codenORGND
dc.identifier.isiut000334571100034
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