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https://doi.org/10.1039/C39910000850
Title: | Synthesis, and spectral and X-ray structural studies of a novel delocalised diphosphazene (CF3)2P=N=PPh3 and the iron carbonyl complexes [Fe(CO)4{(CF3)2P=N=PPh 3}] and [Fe(CO)3{(CF3)2P=N=PPh 3}2] | Authors: | Ang, H.G. Cai, Y.M. Koh, L.L. Kwik, W.L. |
Issue Date: | 1991 | Citation: | Ang, H.G., Cai, Y.M., Koh, L.L., Kwik, W.L. (1991). Synthesis, and spectral and X-ray structural studies of a novel delocalised diphosphazene (CF3)2P=N=PPh3 and the iron carbonyl complexes [Fe(CO)4{(CF3)2P=N=PPh 3}] and [Fe(CO)3{(CF3)2P=N=PPh 3}2]. Journal of the Chemical Society, Chemical Communications (13) : 850-852. ScholarBank@NUS Repository. https://doi.org/10.1039/C39910000850 | Abstract: | The diphosphazene (CF3)2P=N=PPh3 L prepared from the reaction of (CF3)2PN3 with PPh3 has been shown from a single-crystal X-ray structural study to possess an unusual and novel delocalised P=N=P moiety containing PIV and PV atoms; the P=N=P structure is retained upon coordination to Fe in the complexes [Fe(CO)4{(CF3)2P=N=PPh 3}] 1 and [Fe(CO)3{(CF3)2P=N= PPh3}2] 2. | Source Title: | Journal of the Chemical Society, Chemical Communications | URI: | http://scholarbank.nus.edu.sg/handle/10635/95135 | ISSN: | 00224936 | DOI: | 10.1039/C39910000850 |
Appears in Collections: | Staff Publications |
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