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https://doi.org/10.1002/chem.201202504
| Title: | A highly enantioselective synthesis of functionalized 2,3-dihydrofurans by a modified Feist-Bénary reaction | Authors: | Dou, X. Zhong, F. Lu, Y. |
Keywords: | asymmetric synthesis domino reaction Feist-Bénary reaction organocatalysis synthetic methods |
Issue Date: | 29-Oct-2012 | Citation: | Dou, X., Zhong, F., Lu, Y. (2012-10-29). A highly enantioselective synthesis of functionalized 2,3-dihydrofurans by a modified Feist-Bénary reaction. Chemistry - A European Journal 18 (44) : 13945-13948. ScholarBank@NUS Repository. https://doi.org/10.1002/chem.201202504 | Abstract: | Organocatalysis: A modified Feist-Bénary reaction employing acyclic β-ketoesters as the dinucleophile and (E)-β,β-bromo nitrostyrenes as the dielectrophile was developed for the asymmetric synthesis of 2,3-dihydrofurans. L-Threonine-derived tertiary amine/thiourea catalysts were found to be the most efficient catalysts, inducing the reaction in a highly enantioselective manner (see scheme; TBDPS=tert-butyldiphenylsilyl). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | Source Title: | Chemistry - A European Journal | URI: | http://scholarbank.nus.edu.sg/handle/10635/92945 | ISSN: | 09476539 | DOI: | 10.1002/chem.201202504 |
| Appears in Collections: | Staff Publications |
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