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https://doi.org/10.1002/adma.200700086
Title: | Injection-induced de-doping in a conducting polymer during device operation: Asymmetry in the hole injection and extraction rates | Authors: | Chia, P.-J. Chua, L.-L. Sivaramakrishnan, S. Zhuo, J.-M. Zhao, L.-H. Sim, W.-S. Yeo, Y.-C. Ho, P.K.-H. |
Issue Date: | 3-Dec-2007 | Citation: | Chia, P.-J., Chua, L.-L., Sivaramakrishnan, S., Zhuo, J.-M., Zhao, L.-H., Sim, W.-S., Yeo, Y.-C., Ho, P.K.-H. (2007-12-03). Injection-induced de-doping in a conducting polymer during device operation: Asymmetry in the hole injection and extraction rates. Advanced Materials 19 (23) : 4202-4207. ScholarBank@NUS Repository. https://doi.org/10.1002/adma.200700086 | Abstract: | Injection-induced De-doping in a conducting polymer, poly(3,4- ethylenedioxythiophene) (PEDT) poly(styrenesulfonic acid)(PSSH) during device operation was reported. PEDT:PSSH is strongly acidic on account of the excess PSSH, and often contaminated with ions leftover from the oxidation reaction. The hole extraction PEDT+ → PEDT0 + h+ at the negative contact occurs more readily than hole injection from the opposite contact, which builds up a transient population of PEDT+ of a lower oxidation state across the electrode gap. Electrochemistry occurs in PEDT:PSS to give gas evolution and film spalling. The value across a lateral Au electrode gap was mapped using the Raman spectroscopy to determine whether the doping level of PEDT is permanently altered. The de-doping was confirmed by Fourier Transform Infrared Spectroscopy, which shows loss of the doping-induced infrared modes. | Source Title: | Advanced Materials | URI: | http://scholarbank.nus.edu.sg/handle/10635/82543 | ISSN: | 09359648 | DOI: | 10.1002/adma.200700086 |
Appears in Collections: | Staff Publications |
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