Chiral bicyclic guanidine-catalyzed enantioselective reactions of anthrones

Please use this identifier to cite or link to this item: https://doi.org/10.1021/ja064636n

Title:	Chiral bicyclic guanidine-catalyzed enantioselective reactions of anthrones
Authors:	Shen, J. Nguyen, T.T. Goh, Y.-P. Ye, W. Fu, X. Xu, J. Tan, C.-H.
Issue Date:	25-Oct-2006
Citation:	Shen, J., Nguyen, T.T., Goh, Y.-P., Ye, W., Fu, X., Xu, J., Tan, C.-H. (2006-10-25). Chiral bicyclic guanidine-catalyzed enantioselective reactions of anthrones. Journal of the American Chemical Society 128 (42) : 13692-13693. ScholarBank@NUS Repository. https://doi.org/10.1021/ja064636n
Abstract:	Chiral bicyclic guanidine 1 was found to be an excellent catalyst for reactions between anthrones and various dienophiles. The catalyst can tolerate a range of substituents and substitution patterns, making several anthrone derivatives suitable for this reaction. Both Diels-Alder and Michael adducts were obtained in excellent yields, high regioselectivities, and high enantioselectivities. This is the first case of a highly enantioselective base-catalyzed anthrone Diels-Alder reaction. Copyright © 2006 American Chemical Society.
Source Title:	Journal of the American Chemical Society
URI:	http://scholarbank.nus.edu.sg/handle/10635/75745
ISSN:	00027863
DOI:	10.1021/ja064636n
Appears in Collections:	Staff Publications

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