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|Title:||Chiral bicyclic guanidine-catalyzed enantioselective reactions of anthrones|
|Citation:||Shen, J., Nguyen, T.T., Goh, Y.-P., Ye, W., Fu, X., Xu, J., Tan, C.-H. (2006-10-25). Chiral bicyclic guanidine-catalyzed enantioselective reactions of anthrones. Journal of the American Chemical Society 128 (42) : 13692-13693. ScholarBank@NUS Repository. https://doi.org/10.1021/ja064636n|
|Abstract:||Chiral bicyclic guanidine 1 was found to be an excellent catalyst for reactions between anthrones and various dienophiles. The catalyst can tolerate a range of substituents and substitution patterns, making several anthrone derivatives suitable for this reaction. Both Diels-Alder and Michael adducts were obtained in excellent yields, high regioselectivities, and high enantioselectivities. This is the first case of a highly enantioselective base-catalyzed anthrone Diels-Alder reaction. Copyright © 2006 American Chemical Society.|
|Source Title:||Journal of the American Chemical Society|
|Appears in Collections:||Staff Publications|
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