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https://doi.org/10.1002/anie.201304107
| Title: | Catalytic, enantioselective, and highly chemoselective bromocyclization of olefinic dicarbonyl compounds | Authors: | Zhao, Y. Jiang, X. Yeung, Y.-Y. |
Keywords: | asymmetric catalysis chemoselectivity cyclization furans Lewis bases |
Issue Date: | 12-Aug-2013 | Citation: | Zhao, Y., Jiang, X., Yeung, Y.-Y. (2013-08-12). Catalytic, enantioselective, and highly chemoselective bromocyclization of olefinic dicarbonyl compounds. Angewandte Chemie - International Edition 52 (33) : 8597-8601. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201304107 | Abstract: | Overriding preferences: An amine-thiocarbamate catalyst can mediate the facile, efficient, and highly enantioselective bromocyclization of olefinic 1,3-dicarbonyl compounds. In the presence of the bifunctional catalyst, the bromination occurs chemoselectively at the olefinic moiety rather than at the carbon atom in the α-position to the carbonyl units. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | Source Title: | Angewandte Chemie - International Edition | URI: | http://scholarbank.nus.edu.sg/handle/10635/75701 | ISSN: | 14337851 | DOI: | 10.1002/anie.201304107 |
| Appears in Collections: | Staff Publications |
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