Please use this identifier to cite or link to this item: https://doi.org/10.1002/anie.201304107
Title: Catalytic, enantioselective, and highly chemoselective bromocyclization of olefinic dicarbonyl compounds
Authors: Zhao, Y.
Jiang, X.
Yeung, Y.-Y. 
Keywords: asymmetric catalysis
chemoselectivity
cyclization
furans
Lewis bases
Issue Date: 12-Aug-2013
Citation: Zhao, Y., Jiang, X., Yeung, Y.-Y. (2013-08-12). Catalytic, enantioselective, and highly chemoselective bromocyclization of olefinic dicarbonyl compounds. Angewandte Chemie - International Edition 52 (33) : 8597-8601. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201304107
Abstract: Overriding preferences: An amine-thiocarbamate catalyst can mediate the facile, efficient, and highly enantioselective bromocyclization of olefinic 1,3-dicarbonyl compounds. In the presence of the bifunctional catalyst, the bromination occurs chemoselectively at the olefinic moiety rather than at the carbon atom in the α-position to the carbonyl units. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Source Title: Angewandte Chemie - International Edition
URI: http://scholarbank.nus.edu.sg/handle/10635/75701
ISSN: 14337851
DOI: 10.1002/anie.201304107
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