Please use this identifier to cite or link to this item:
|Title:||Controlled micropatterning of a Si(100) surface by combined nitroxide-mediated and atom transfer radical polymerizations||Authors:||Xu, F.J.
|Issue Date:||26-Jul-2005||Citation:||Xu, F.J., Song, Y., Cheng, Z.P., Zhu, X.L., Zhu, C.X., Kang, E.T., Neoh, K.G. (2005-07-26). Controlled micropatterning of a Si(100) surface by combined nitroxide-mediated and atom transfer radical polymerizations. Macromolecules 38 (15) : 6254-6258. ScholarBank@NUS Repository. https://doi.org/10.1021/ma050581i||Abstract:||The micropatterning of different polymer brushes, as well as their diblock copolymer brushes on a Si (100) surface using alternating nitroxide-mediated radical polymerization (NMRP) and atom transfer radical polymerization (ATRP) was analyzed. The ATRP initiators were covalently immobilized using robust Si-C bonds in the H-terminated silicon microdomains. The NMRP initiators were coupled to the oxide-covered microdomains of the resist-patterned silicon surface. The results show that the C-Cl bond in the ATRP initiator was relatively stable and did not act as a chain transfer agent during NMRP.||Source Title:||Macromolecules||URI:||http://scholarbank.nus.edu.sg/handle/10635/55422||ISSN:||00249297||DOI:||10.1021/ma050581i|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Jan 17, 2020
WEB OF SCIENCETM
checked on Jan 9, 2020
checked on Dec 30, 2019
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.