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https://doi.org/10.1002/anie.201304642
| Title: | Synthesis and Characterization of a Two-Coordinate Manganese Complex and its Reaction with Molecular Hydrogen at Room Temperature | Authors: | Samuel, Prinson P Mondal, Kartik Chandra Roesky, Herbert W Hermann, Markus Frenking, Gernot Demeshko, Serhiy Meyer, Franc Stueckl, A Claudia Christian, Jonathan H Dalal, Naresh S Ungur, Liviu Chibotaru, Liviu F Proepper, Kevin Meents, Alke Dittrich, Birger |
Keywords: | Science & Technology Physical Sciences Chemistry, Multidisciplinary Chemistry coordination modes cyclic alkyl(amino)carbene density functional calculations dihydrogen splitting manganese TRANSITION-METAL-COMPLEXES ALKYL AMINO CARBENES ACTIVATION COMPOUND BULKY IONS |
Issue Date: | 4-Nov-2013 | Publisher: | WILEY-V C H VERLAG GMBH | Citation: | Samuel, Prinson P, Mondal, Kartik Chandra, Roesky, Herbert W, Hermann, Markus, Frenking, Gernot, Demeshko, Serhiy, Meyer, Franc, Stueckl, A Claudia, Christian, Jonathan H, Dalal, Naresh S, Ungur, Liviu, Chibotaru, Liviu F, Proepper, Kevin, Meents, Alke, Dittrich, Birger (2013-11-04). Synthesis and Characterization of a Two-Coordinate Manganese Complex and its Reaction with Molecular Hydrogen at Room Temperature. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 52 (45) : 11817-11821. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201304642 | Abstract: | The (cAAC)2Mn complex (cAAC=cyclic alkyl(amino)carbene) features a linear two-coordinate Mn-center. The antiferromagnetic coupling of a radical electron, delocalized on two carbene C-atoms, with the central MnI having d6 electronic configuration, mainly contributes to the S T=3/2 ground state. Treatment of (cAAC) 2Mn with H2 at RT resulted in the addition of H-atoms at both "carbene" C-atoms, leaving the central Mn-atom in the S T=5/2 spin ground state. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | Source Title: | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | URI: | https://scholarbank.nus.edu.sg/handle/10635/228849 | ISSN: | 14337851 15213773 |
DOI: | 10.1002/anie.201304642 |
| Appears in Collections: | Elements Staff Publications |
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| File | Description | Size | Format | Access Settings | Version | |
|---|---|---|---|---|---|---|
| Samuel_Angew_2013.pdf | Published version | 798.37 kB | Adobe PDF | CLOSED | None | |
| Samuel_Angew_2013.cif.txt | Supporting information | 43.29 kB | Text | CLOSED | None | |
| Samuel_Angew_2013_SI.pdf | Supporting information | 2.06 MB | Adobe PDF | CLOSED | None |
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