Please use this identifier to cite or link to this item:
https://doi.org/10.1002/anie.201304642
DC Field | Value | |
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dc.title | Synthesis and Characterization of a Two-Coordinate Manganese Complex and its Reaction with Molecular Hydrogen at Room Temperature | |
dc.contributor.author | Samuel, Prinson P | |
dc.contributor.author | Mondal, Kartik Chandra | |
dc.contributor.author | Roesky, Herbert W | |
dc.contributor.author | Hermann, Markus | |
dc.contributor.author | Frenking, Gernot | |
dc.contributor.author | Demeshko, Serhiy | |
dc.contributor.author | Meyer, Franc | |
dc.contributor.author | Stueckl, A Claudia | |
dc.contributor.author | Christian, Jonathan H | |
dc.contributor.author | Dalal, Naresh S | |
dc.contributor.author | Ungur, Liviu | |
dc.contributor.author | Chibotaru, Liviu F | |
dc.contributor.author | Proepper, Kevin | |
dc.contributor.author | Meents, Alke | |
dc.contributor.author | Dittrich, Birger | |
dc.date.accessioned | 2022-07-19T12:53:51Z | |
dc.date.available | 2022-07-19T12:53:51Z | |
dc.date.issued | 2013-11-04 | |
dc.identifier.citation | Samuel, Prinson P, Mondal, Kartik Chandra, Roesky, Herbert W, Hermann, Markus, Frenking, Gernot, Demeshko, Serhiy, Meyer, Franc, Stueckl, A Claudia, Christian, Jonathan H, Dalal, Naresh S, Ungur, Liviu, Chibotaru, Liviu F, Proepper, Kevin, Meents, Alke, Dittrich, Birger (2013-11-04). Synthesis and Characterization of a Two-Coordinate Manganese Complex and its Reaction with Molecular Hydrogen at Room Temperature. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 52 (45) : 11817-11821. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201304642 | |
dc.identifier.issn | 14337851 | |
dc.identifier.issn | 15213773 | |
dc.identifier.uri | https://scholarbank.nus.edu.sg/handle/10635/228849 | |
dc.description.abstract | The (cAAC)2Mn complex (cAAC=cyclic alkyl(amino)carbene) features a linear two-coordinate Mn-center. The antiferromagnetic coupling of a radical electron, delocalized on two carbene C-atoms, with the central MnI having d6 electronic configuration, mainly contributes to the S T=3/2 ground state. Treatment of (cAAC) 2Mn with H2 at RT resulted in the addition of H-atoms at both "carbene" C-atoms, leaving the central Mn-atom in the S T=5/2 spin ground state. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | |
dc.language.iso | en | |
dc.publisher | WILEY-V C H VERLAG GMBH | |
dc.source | Elements | |
dc.subject | Science & Technology | |
dc.subject | Physical Sciences | |
dc.subject | Chemistry, Multidisciplinary | |
dc.subject | Chemistry | |
dc.subject | coordination modes | |
dc.subject | cyclic alkyl(amino)carbene | |
dc.subject | density functional calculations | |
dc.subject | dihydrogen splitting | |
dc.subject | manganese | |
dc.subject | TRANSITION-METAL-COMPLEXES | |
dc.subject | ALKYL AMINO CARBENES | |
dc.subject | ACTIVATION | |
dc.subject | COMPOUND | |
dc.subject | BULKY | |
dc.subject | IONS | |
dc.type | Article | |
dc.date.updated | 2022-07-15T01:51:03Z | |
dc.contributor.department | DEPT OF CHEMISTRY | |
dc.description.doi | 10.1002/anie.201304642 | |
dc.description.sourcetitle | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | |
dc.description.volume | 52 | |
dc.description.issue | 45 | |
dc.description.page | 11817-11821 | |
dc.published.state | Published | |
Appears in Collections: | Elements Staff Publications |
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File | Description | Size | Format | Access Settings | Version | |
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Samuel_Angew_2013.pdf | Published version | 798.37 kB | Adobe PDF | CLOSED | None | |
Samuel_Angew_2013.cif.txt | Supporting information | 43.29 kB | Text | CLOSED | None | |
Samuel_Angew_2013_SI.pdf | Supporting information | 2.06 MB | Adobe PDF | CLOSED | None |
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