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https://doi.org/10.1021/ic301784m
Title: | Heterometallic Tetranuclear [Ln(2)(III)Co(2)(III)] Complexes Including Suppression of Quantum Tunneling of Magnetization in the [(Dy2Co2III)-Co-III] Single Molecule Magnet | Authors: | Langley, Stuart K Chilton, Nicholas F Ungur, Liviu Moubaraki, Boujemaa Chibotaru, Liviu F Murray, Keith S |
Keywords: | Science & Technology Physical Sciences Chemistry, Inorganic & Nuclear Chemistry NUCLEAR-SPIN RELAXATION FAMILY |
Issue Date: | 5-Nov-2012 | Publisher: | AMER CHEMICAL SOC | Citation: | Langley, Stuart K, Chilton, Nicholas F, Ungur, Liviu, Moubaraki, Boujemaa, Chibotaru, Liviu F, Murray, Keith S (2012-11-05). Heterometallic Tetranuclear [Ln(2)(III)Co(2)(III)] Complexes Including Suppression of Quantum Tunneling of Magnetization in the [(Dy2Co2III)-Co-III] Single Molecule Magnet. INORGANIC CHEMISTRY 51 (21) : 11873-11881. ScholarBank@NUS Repository. https://doi.org/10.1021/ic301784m | Abstract: | Using a heterometallic approach the synthesis, structures, and magnetic properties are reported for the complexes [Ln III2Co III2(OMe) 2(teaH) 2(O 2CPh) 4(MeOH) 4](NO 3) 2·MeOH·H 2O {Ln = Gd (1a), Tb (2a), and Dy (3a)} and [Ln III2Co III2(OMe) 2(teaH) 2(O 2CPh) 4(MeOH) 2(NO 3) 2]·MeOH·H 2O {Ln = Gd (1b), Tb (2b), and Dy (3b)}. Both compounds for the respective lanthanide ions are found to be isolated within the same crystal. Each Ln III dinuclear unit is incorporated within a diamagnetic Co III/organic ligand backbone utilizing triethanolamine and benzoic acid as bridging ligands. Magnetic studies reveal an absence of any observable coupling interaction for the Gd case. The Dy analogue displays single molecule magnet (SMM) behavior with a large energy barrier to magnetization reversal of 88.8 K, and the quantum tunneling of the magnetization (QTM) is effectively suppressed because of the nonmagnetic exchange ground state of the molecule. Dilution of the Dy complex into an isostructural diamagnetic yttrium matrix allowed us to determine aspects of the relaxation mechanism within the system. © 2012 American Chemical Society. | Source Title: | INORGANIC CHEMISTRY | URI: | https://scholarbank.nus.edu.sg/handle/10635/228847 | ISSN: | 00201669 1520510X |
DOI: | 10.1021/ic301784m |
Appears in Collections: | Staff Publications Elements |
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Langley_IC_2012.cif.txt | Supporting information | 148.76 kB | Text | CLOSED | None | |
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Langley_IC_2012_SI.pdf | Supporting information | 2.21 MB | Adobe PDF | CLOSED | None |
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