Please use this identifier to cite or link to this item: https://doi.org/10.1021/ic301784m
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dc.titleHeterometallic Tetranuclear [Ln(2)(III)Co(2)(III)] Complexes Including Suppression of Quantum Tunneling of Magnetization in the [(Dy2Co2III)-Co-III] Single Molecule Magnet
dc.contributor.authorLangley, Stuart K
dc.contributor.authorChilton, Nicholas F
dc.contributor.authorUngur, Liviu
dc.contributor.authorMoubaraki, Boujemaa
dc.contributor.authorChibotaru, Liviu F
dc.contributor.authorMurray, Keith S
dc.date.accessioned2022-07-19T12:29:46Z
dc.date.available2022-07-19T12:29:46Z
dc.date.issued2012-11-05
dc.identifier.citationLangley, Stuart K, Chilton, Nicholas F, Ungur, Liviu, Moubaraki, Boujemaa, Chibotaru, Liviu F, Murray, Keith S (2012-11-05). Heterometallic Tetranuclear [Ln(2)(III)Co(2)(III)] Complexes Including Suppression of Quantum Tunneling of Magnetization in the [(Dy2Co2III)-Co-III] Single Molecule Magnet. INORGANIC CHEMISTRY 51 (21) : 11873-11881. ScholarBank@NUS Repository. https://doi.org/10.1021/ic301784m
dc.identifier.issn00201669
dc.identifier.issn1520510X
dc.identifier.urihttps://scholarbank.nus.edu.sg/handle/10635/228847
dc.description.abstractUsing a heterometallic approach the synthesis, structures, and magnetic properties are reported for the complexes [Ln III2Co III2(OMe) 2(teaH) 2(O 2CPh) 4(MeOH) 4](NO 3) 2·MeOH·H 2O {Ln = Gd (1a), Tb (2a), and Dy (3a)} and [Ln III2Co III2(OMe) 2(teaH) 2(O 2CPh) 4(MeOH) 2(NO 3) 2]·MeOH·H 2O {Ln = Gd (1b), Tb (2b), and Dy (3b)}. Both compounds for the respective lanthanide ions are found to be isolated within the same crystal. Each Ln III dinuclear unit is incorporated within a diamagnetic Co III/organic ligand backbone utilizing triethanolamine and benzoic acid as bridging ligands. Magnetic studies reveal an absence of any observable coupling interaction for the Gd case. The Dy analogue displays single molecule magnet (SMM) behavior with a large energy barrier to magnetization reversal of 88.8 K, and the quantum tunneling of the magnetization (QTM) is effectively suppressed because of the nonmagnetic exchange ground state of the molecule. Dilution of the Dy complex into an isostructural diamagnetic yttrium matrix allowed us to determine aspects of the relaxation mechanism within the system. © 2012 American Chemical Society.
dc.language.isoen
dc.publisherAMER CHEMICAL SOC
dc.sourceElements
dc.subjectScience & Technology
dc.subjectPhysical Sciences
dc.subjectChemistry, Inorganic & Nuclear
dc.subjectChemistry
dc.subjectNUCLEAR-SPIN
dc.subjectRELAXATION
dc.subjectFAMILY
dc.typeArticle
dc.date.updated2022-07-15T01:38:24Z
dc.contributor.departmentDEPT OF CHEMISTRY
dc.description.doi10.1021/ic301784m
dc.description.sourcetitleINORGANIC CHEMISTRY
dc.description.volume51
dc.description.issue21
dc.description.page11873-11881
dc.published.statePublished
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