Please use this identifier to cite or link to this item: https://doi.org/10.1039/c9qo00471h
Title: Creation of bispiro[pyrazolone-3,3 '-oxindoles] via a phosphine-catalyzed enantioselective [3+2] annulation of the Morita-Baylis-Hillman carbonates with pyrazoloneyldiene oxindoles
Authors: Zhang, Jing
Chan, Wai-Lun
Chen, Ligong
Ullah, Nisar
Lu, Yixin 
Keywords: Science & Technology
Physical Sciences
Chemistry, Organic
Chemistry
MICHAEL ADDITION
CONSTRUCTION
CASCADE
ALLENES
SPIROOXINDOLES
ALLENOATES
DISCOVERY
KETIMINES
DESIGN
POTENT
Issue Date: 7-Jul-2019
Publisher: ROYAL SOC CHEMISTRY
Citation: Zhang, Jing, Chan, Wai-Lun, Chen, Ligong, Ullah, Nisar, Lu, Yixin (2019-07-07). Creation of bispiro[pyrazolone-3,3 '-oxindoles] via a phosphine-catalyzed enantioselective [3+2] annulation of the Morita-Baylis-Hillman carbonates with pyrazoloneyldiene oxindoles. ORGANIC CHEMISTRY FRONTIERS 6 (13) : 2210-2214. ScholarBank@NUS Repository. https://doi.org/10.1039/c9qo00471h
Abstract: © the Partner Organisations 2019. A [3 + 2] annulation between the Morita-Baylis-Hillman (MBH) carbonates and pyrazoloneyldiene oxindoles catalyzed by (S)-SITCP has been developed. Structurally novel bispiro[pyrazolone-3,3′-oxindoles] containing two contiguous quaternary stereogenic centers were created in excellent yields, in a diastereospecific and highly enantioselective manner.
Source Title: ORGANIC CHEMISTRY FRONTIERS
URI: https://scholarbank.nus.edu.sg/handle/10635/169692
ISSN: 20524129
DOI: 10.1039/c9qo00471h
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