Please use this identifier to cite or link to this item: https://doi.org/10.1002/anie.202002724
Title: Divergent Chemistry Paths for 3D and 1D Metallo-Covalent Organic Frameworks.
Authors: Xu, Hai-Sen
Luo, Yi
SEE PEI ZHEN 
LI XING 
Chen, Zhongxin
Zhou, Yi
Zhao, Xiaoxu
Leng, Kai
PARK IN-HYEOK 
LI RUNLAI 
LIU CUIBO 
Chen, Fangzheng
Xi, Shibo
Sun, Junliang
LOH KIAN PING 
Keywords: 3D and 1D
Structure elucidation
covalent organic frameworks
metal templates
self assembly
Issue Date: 4-Apr-2020
Publisher: Wiley
Citation: Xu, Hai-Sen, Luo, Yi, SEE PEI ZHEN, LI XING, Chen, Zhongxin, Zhou, Yi, Zhao, Xiaoxu, Leng, Kai, PARK IN-HYEOK, LI RUNLAI, LIU CUIBO, Chen, Fangzheng, Xi, Shibo, Sun, Junliang, LOH KIAN PING (2020-04-04). Divergent Chemistry Paths for 3D and 1D Metallo-Covalent Organic Frameworks.. Angewandte Chemie (International ed. in English). ScholarBank@NUS Repository. https://doi.org/10.1002/anie.202002724
Abstract: The marriage of dynamic covalent chemistry (DCC) and coordination chemistry is a powerful tool for assembling complex architectures from simple building units. Recently, the synthesis of woven covalent organic frameworks (COFs) with topologically fascinating structures has been achieved using this approach. However, the scope is highly limited and there is a need to discover new pathways that can assemble covalently linked organic threads into crystalline frameworks. Here, we have identified branching pathways leading to the assembly of three-dimensional (3D) woven COFs or one-dimensional (1D) metallo-COFs (mCOFs), where the mechanism is underpinned by the absence or presence of ligand exchange.
Source Title: Angewandte Chemie (International ed. in English)
URI: https://scholarbank.nus.edu.sg/handle/10635/167695
ISSN: 1433-7851
1521-3773
DOI: 10.1002/anie.202002724
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