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https://doi.org/10.1016/j.jorganchem.2008.04.040
Title: | Reaction of [M(CO)4]- (M = Ir, Rh) with cyclopropenyl tetrafluoroborate - Ring opening and coupling of cyclopropenyl ligands to form dinuclear metal complexes | Authors: | Chan, P.K. Leong, W.K. |
Keywords: | C-C coupling Cyclopropenyl Diiridium Ring opening |
Issue Date: | 15-Jul-2008 | Citation: | Chan, P.K., Leong, W.K. (2008-07-15). Reaction of [M(CO)4]- (M = Ir, Rh) with cyclopropenyl tetrafluoroborate - Ring opening and coupling of cyclopropenyl ligands to form dinuclear metal complexes. Journal of Organometallic Chemistry 693 (15) : 2641-2644. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2008.04.040 | Abstract: | Reaction of the iridium tetracarbonylate [PPN][Ir(CO)4] (1a) with triphenylcyclopropenyl tetrafluoroborate [C3Ph3][BF4] afforded two dinuclear species Ir2(CO)4(μ,η1:η2- C3Ph3)(μ,η2:η3 -C3Ph3) (2) and Ir2(CO)4(μ,η4:η4- C6Ph6) (3a) resulting from the ring opening and in the latter case, coupling of the resulting acyclic, propenyl ligands. The analogous reaction with [PPN][Rh(CO)4] (1b) afforded only the rhodium analogue for 3a. © 2008 Elsevier B.V. All rights reserved. | Source Title: | Journal of Organometallic Chemistry | URI: | http://scholarbank.nus.edu.sg/handle/10635/95538 | ISSN: | 0022328X | DOI: | 10.1016/j.jorganchem.2008.04.040 |
Appears in Collections: | Staff Publications |
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