Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2008.04.040
DC FieldValue
dc.titleReaction of [M(CO)4]- (M = Ir, Rh) with cyclopropenyl tetrafluoroborate - Ring opening and coupling of cyclopropenyl ligands to form dinuclear metal complexes
dc.contributor.authorChan, P.K.
dc.contributor.authorLeong, W.K.
dc.date.accessioned2014-10-16T08:49:03Z
dc.date.available2014-10-16T08:49:03Z
dc.date.issued2008-07-15
dc.identifier.citationChan, P.K., Leong, W.K. (2008-07-15). Reaction of [M(CO)4]- (M = Ir, Rh) with cyclopropenyl tetrafluoroborate - Ring opening and coupling of cyclopropenyl ligands to form dinuclear metal complexes. Journal of Organometallic Chemistry 693 (15) : 2641-2644. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2008.04.040
dc.identifier.issn0022328X
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/95538
dc.description.abstractReaction of the iridium tetracarbonylate [PPN][Ir(CO)4] (1a) with triphenylcyclopropenyl tetrafluoroborate [C3Ph3][BF4] afforded two dinuclear species Ir2(CO)4(μ,η1:η2- C3Ph3)(μ,η2:η3 -C3Ph3) (2) and Ir2(CO)4(μ,η4:η4- C6Ph6) (3a) resulting from the ring opening and in the latter case, coupling of the resulting acyclic, propenyl ligands. The analogous reaction with [PPN][Rh(CO)4] (1b) afforded only the rhodium analogue for 3a. © 2008 Elsevier B.V. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.jorganchem.2008.04.040
dc.sourceScopus
dc.subjectC-C coupling
dc.subjectCyclopropenyl
dc.subjectDiiridium
dc.subjectRing opening
dc.typeOthers
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1016/j.jorganchem.2008.04.040
dc.description.sourcetitleJournal of Organometallic Chemistry
dc.description.volume693
dc.description.issue15
dc.description.page2641-2644
dc.description.codenJORCA
dc.identifier.isiut000257290900025
Appears in Collections:Staff Publications

Show simple item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

1
checked on Apr 7, 2021

WEB OF SCIENCETM
Citations

1
checked on Apr 7, 2021

Page view(s)

88
checked on Apr 11, 2021

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.