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| Title: | The heteronuclear cluster RuOs3(μ-H)2(CO)13 - A high yield synthesis, isomerism and a triphenylphosphine derivative | Authors: | Pereira, L. Leong, W.K. Wong, S.Y. |
Keywords: | Clusters Heteronuclear Hydride Isomers Osmium Ruthenium |
Issue Date: | 8-Sep-2000 | Citation: | Pereira, L.,Leong, W.K.,Wong, S.Y. (2000-09-08). The heteronuclear cluster RuOs3(μ-H)2(CO)13 - A high yield synthesis, isomerism and a triphenylphosphine derivative. Journal of Organometallic Chemistry 609 (1-2) : 104-109. ScholarBank@NUS Repository. | Abstract: | A high-yielding alternative synthesis of the heteronuclear cluster RuOs3(μ-H)2(CO)13 has been developed. It is also demonstrated that the cluster exists as at least three isomers, which rapidly interconvert in solution. A triphenylphosphine derivative, RuOs3(μ-H)2(CO)12(PPh3), has also been prepared; this exists as two isomers, both of which have been characterised by single-crystal X-ray crystallographic studies. © 2000 Elsevier Science S.A. All rights reserved. | Source Title: | Journal of Organometallic Chemistry | URI: | http://scholarbank.nus.edu.sg/handle/10635/95236 | ISSN: | 0022328X |
| Appears in Collections: | Staff Publications |
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