Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/95236
Title: The heteronuclear cluster RuOs3(μ-H)2(CO)13 - A high yield synthesis, isomerism and a triphenylphosphine derivative
Authors: Pereira, L.
Leong, W.K. 
Wong, S.Y. 
Keywords: Clusters
Heteronuclear
Hydride
Isomers
Osmium
Ruthenium
Issue Date: 8-Sep-2000
Citation: Pereira, L.,Leong, W.K.,Wong, S.Y. (2000-09-08). The heteronuclear cluster RuOs3(μ-H)2(CO)13 - A high yield synthesis, isomerism and a triphenylphosphine derivative. Journal of Organometallic Chemistry 609 (1-2) : 104-109. ScholarBank@NUS Repository.
Abstract: A high-yielding alternative synthesis of the heteronuclear cluster RuOs3(μ-H)2(CO)13 has been developed. It is also demonstrated that the cluster exists as at least three isomers, which rapidly interconvert in solution. A triphenylphosphine derivative, RuOs3(μ-H)2(CO)12(PPh3), has also been prepared; this exists as two isomers, both of which have been characterised by single-crystal X-ray crystallographic studies. © 2000 Elsevier Science S.A. All rights reserved.
Source Title: Journal of Organometallic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/95236
ISSN: 0022328X
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

Page view(s)

24
checked on Jul 6, 2018

Google ScholarTM

Check


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.