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|Title:||The heteronuclear cluster RuOs3(μ-H)2(CO)13 - A high yield synthesis, isomerism and a triphenylphosphine derivative|
|Citation:||Pereira, L.,Leong, W.K.,Wong, S.Y. (2000-09-08). The heteronuclear cluster RuOs3(μ-H)2(CO)13 - A high yield synthesis, isomerism and a triphenylphosphine derivative. Journal of Organometallic Chemistry 609 (1-2) : 104-109. ScholarBank@NUS Repository.|
|Abstract:||A high-yielding alternative synthesis of the heteronuclear cluster RuOs3(μ-H)2(CO)13 has been developed. It is also demonstrated that the cluster exists as at least three isomers, which rapidly interconvert in solution. A triphenylphosphine derivative, RuOs3(μ-H)2(CO)12(PPh3), has also been prepared; this exists as two isomers, both of which have been characterised by single-crystal X-ray crystallographic studies. © 2000 Elsevier Science S.A. All rights reserved.|
|Source Title:||Journal of Organometallic Chemistry|
|Appears in Collections:||Staff Publications|
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