Synthesis, complexation, and supramolecular assembly of 21,30-dithia-17,25-dimethyl-1,4,7,10,13-pentaoxa[13.3.3](1,2,6)cyclophane

Please use this identifier to cite or link to this item: https://doi.org/10.1021/ol026374+

Title:	Synthesis, complexation, and supramolecular assembly of 21,30-dithia-17,25-dimethyl-1,4,7,10,13-pentaoxa[13.3.3](1,2,6)cyclophane
Authors:	Xu, J. Lai, Y.-H.
Issue Date:	19-Sep-2002
Citation:	Xu, J., Lai, Y.-H. (2002-09-19). Synthesis, complexation, and supramolecular assembly of 21,30-dithia-17,25-dimethyl-1,4,7,10,13-pentaoxa[13.3.3](1,2,6)cyclophane. Organic Letters 4 (19) : 3211-3214. ScholarBank@NUS Repository. https://doi.org/10.1021/ol026374+
Abstract:	A crownophane consisting of a dithia[3.3]metacyclophane moiety was synthesized by employing a high dilution method. The crystal structure and complexation behavior of this crownophane was studied. A hydrogen-bonded linear supramolecular assembly using anion-Na+-crownophane-solvent as a synthon was observed in the solid state. This supramolecular assembly was also stabilized via an intermolecular S⋯H-C interaction.
Source Title:	Organic Letters
URI:	http://scholarbank.nus.edu.sg/handle/10635/95154
ISSN:	15237060
DOI:	10.1021/ol026374+
Appears in Collections:	Staff Publications

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