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|Title:||Synthesis, complexation, and supramolecular assembly of 21,30-dithia-17,25-dimethyl-1,4,7,10,13-pentaoxa[13.3.3](1,2,6)cyclophane|
|Citation:||Xu, J., Lai, Y.-H. (2002-09-19). Synthesis, complexation, and supramolecular assembly of 21,30-dithia-17,25-dimethyl-1,4,7,10,13-pentaoxa[13.3.3](1,2,6)cyclophane. Organic Letters 4 (19) : 3211-3214. ScholarBank@NUS Repository. https://doi.org/10.1021/ol026374+|
|Abstract:||A crownophane consisting of a dithia[3.3]metacyclophane moiety was synthesized by employing a high dilution method. The crystal structure and complexation behavior of this crownophane was studied. A hydrogen-bonded linear supramolecular assembly using anion-Na+-crownophane-solvent as a synthon was observed in the solid state. This supramolecular assembly was also stabilized via an intermolecular S⋯H-C interaction.|
|Source Title:||Organic Letters|
|Appears in Collections:||Staff Publications|
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