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https://doi.org/10.1016/j.jorganchem.2007.09.029
| Title: | Suzuki coupling catalyzed by a homoleptic Pd(I)-Pd(I) solvento complex | Authors: | Han, X. Weng, Z. Hor, T.S.A. |
Keywords: | Catalyst Dinuclear Homoleptic Palladium Suzuki coupling |
Issue Date: | 15-Dec-2007 | Citation: | Han, X., Weng, Z., Hor, T.S.A. (2007-12-15). Suzuki coupling catalyzed by a homoleptic Pd(I)-Pd(I) solvento complex. Journal of Organometallic Chemistry 692 (26) : 5690-5696. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2007.09.029 | Abstract: | The PdI-PdI bonded complex [Pd2(CH3CN)6][SbF6] 2 is catalytically active towards Suzuki cross-coupling reactions of aryl bromides or chlorides with various arylboronic acids under mild conditions giving good to excellent yields. Its performance is enhanced by the introduction of stoichiometric or limited phosphines. The effects of different ligands, metal oxidation states [Pd(II), Pd(I) Pd(0)], bases and solvents have been examined. © 2007 Elsevier B.V. All rights reserved. | Source Title: | Journal of Organometallic Chemistry | URI: | http://scholarbank.nus.edu.sg/handle/10635/94993 | ISSN: | 0022328X | DOI: | 10.1016/j.jorganchem.2007.09.029 |
| Appears in Collections: | Staff Publications |
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