Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2007.09.029
Title: Suzuki coupling catalyzed by a homoleptic Pd(I)-Pd(I) solvento complex
Authors: Han, X.
Weng, Z. 
Hor, T.S.A. 
Keywords: Catalyst
Dinuclear
Homoleptic
Palladium
Suzuki coupling
Issue Date: 15-Dec-2007
Citation: Han, X., Weng, Z., Hor, T.S.A. (2007-12-15). Suzuki coupling catalyzed by a homoleptic Pd(I)-Pd(I) solvento complex. Journal of Organometallic Chemistry 692 (26) : 5690-5696. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2007.09.029
Abstract: The PdI-PdI bonded complex [Pd2(CH3CN)6][SbF6] 2 is catalytically active towards Suzuki cross-coupling reactions of aryl bromides or chlorides with various arylboronic acids under mild conditions giving good to excellent yields. Its performance is enhanced by the introduction of stoichiometric or limited phosphines. The effects of different ligands, metal oxidation states [Pd(II), Pd(I) Pd(0)], bases and solvents have been examined. © 2007 Elsevier B.V. All rights reserved.
Source Title: Journal of Organometallic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/94993
ISSN: 0022328X
DOI: 10.1016/j.jorganchem.2007.09.029
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