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| Title: | Solid-state self-assembly of a complex from 1,3,5-benzenetricarboxylic acid and 1,3,5-trihydroxybenzene: Influence of strong O-H···O and C-H···O hydrogen bonds | Authors: | Liu, R. Mok, K.-F. Valiyaveettil, S. |
Issue Date: | 2001 | Citation: | Liu, R., Mok, K.-F., Valiyaveettil, S. (2001). Solid-state self-assembly of a complex from 1,3,5-benzenetricarboxylic acid and 1,3,5-trihydroxybenzene: Influence of strong O-H···O and C-H···O hydrogen bonds. New Journal of Chemistry 25 (7) : 890-892. ScholarBank@NUS Repository. | Abstract: | 1,3,5-Benzenetricarboxylic acid (trimesic acid, TMA) was cocrystallized with 0.5 equiv. of 1,3,5-trihydroxybenzene (phloroglucinol, THB) to generate a close-packed non-interpenetrating planar mosaic motif. Both O-H···O and C-H···O hydrogen bonds were observed in the crystal lattice. Each THB molecule is hydrogen bonded to six adjacent TMA molecules to form a planar rosette-shaped structure, which constitutes the repeating units of a layer-type lattice. | Source Title: | New Journal of Chemistry | URI: | http://scholarbank.nus.edu.sg/handle/10635/94838 | ISSN: | 11440546 |
| Appears in Collections: | Staff Publications |
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