Resolution and enantiomeric purities of [2-(methylsulfinyl)ethyl]amine

Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/94717

DC Field	Value
dc.title	Resolution and enantiomeric purities of [2-(methylsulfinyl)ethyl]amine
dc.contributor.author	Lim, C.-C.
dc.contributor.author	Leung, P.-H.
dc.contributor.author	Sim, K.Y.
dc.date.accessioned	2014-10-16T08:39:17Z
dc.date.available	2014-10-16T08:39:17Z
dc.date.issued	1994-10
dc.identifier.citation	Lim, C.-C.,Leung, P.-H.,Sim, K.Y. (1994-10). Resolution and enantiomeric purities of [2-(methylsulfinyl)ethyl]amine. Tetrahedron: Asymmetry 5 (10) : 1883-1886. ScholarBank@NUS Repository.
dc.identifier.issn	09574166
dc.identifier.uri	http://scholarbank.nus.edu.sg/handle/10635/94717
dc.description.abstract	A resolution of the asymmetric ligand H2NCH2CH2S(O)Me, (±)-1, has been achieved by using (R)-[(acetonitrile)[1-[1-(dimethylamino)ethyl]-2-naphthalenyl](triphenyl-phosphine)]palladium(II) perchlorate as the resolving agent. The (S)- enantiomer, with [α]D -136.8 (c = 1.0, EtOH), was liberated from the less soluble diastereomeric complex by treatment with triphenylphosphine in dichloromethane. The enantiomeric purity of the amino-sulfoxide has been confirmed by NMR studies. © 1994.
dc.source	Scopus
dc.type	Article
dc.contributor.department	CHEMISTRY
dc.description.sourcetitle	Tetrahedron: Asymmetry
dc.description.volume	5
dc.description.issue	10
dc.description.page	1883-1886
dc.description.coden	TASYE
dc.identifier.isiut	NOT_IN_WOS
Appears in Collections:	Staff Publications

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