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|Title:||Pd(II) complexes with mixed benzothiazolin-2-ylidene and phosphine ligands and their catalytic activities toward C-C coupling reactions||Authors:||Yen, S.K.
|Issue Date:||2008||Citation:||Yen, S.K., Koh, L.L., Huynh, H.V., Hor, T.S.A. (2008). Pd(II) complexes with mixed benzothiazolin-2-ylidene and phosphine ligands and their catalytic activities toward C-C coupling reactions. Dalton Transactions (5) : 699-706. ScholarBank@NUS Repository. https://doi.org/10.1039/b713152f||Abstract:||Novel Pd(ii) mixed N,S-heterocyclic carbene (NSHC)-phosphine complexes of the general formula [PdBr2(NSHC)(PR3)] were obtained from bridge cleavage of dinuclear NSHC complexes of type [PdBr2(NSHC)] 2 [NSHC = 3-benzylbenzothiazolin-2-ylidene and 3- propylbenzothiazolin-2-ylidene] with triphenylphosphine, tricyclohexylphosphine and 2-diphenylphosphanyl-pyridine. All complexes have been fully characterized by 1H and 13C NMR spectroscopy, ESI mass spectrometry and elemental analysis. The X-ray crystal structures of complexes 3-8 are reported. The complexes exhibit moderate to good catalytic activity in the Suzuki-Miyaura coupling reaction of aryl bromides and chlorides. © The Royal Society of Chemistry 2008.||Source Title:||Dalton Transactions||URI:||http://scholarbank.nus.edu.sg/handle/10635/94488||ISSN:||14779226||DOI:||10.1039/b713152f|
|Appears in Collections:||Staff Publications|
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