Please use this identifier to cite or link to this item: https://doi.org/10.1039/b713152f
Title: Pd(II) complexes with mixed benzothiazolin-2-ylidene and phosphine ligands and their catalytic activities toward C-C coupling reactions
Authors: Yen, S.K. 
Koh, L.L. 
Huynh, H.V. 
Hor, T.S.A. 
Issue Date: 2008
Citation: Yen, S.K., Koh, L.L., Huynh, H.V., Hor, T.S.A. (2008). Pd(II) complexes with mixed benzothiazolin-2-ylidene and phosphine ligands and their catalytic activities toward C-C coupling reactions. Dalton Transactions (5) : 699-706. ScholarBank@NUS Repository. https://doi.org/10.1039/b713152f
Abstract: Novel Pd(ii) mixed N,S-heterocyclic carbene (NSHC)-phosphine complexes of the general formula [PdBr2(NSHC)(PR3)] were obtained from bridge cleavage of dinuclear NSHC complexes of type [PdBr2(NSHC)] 2 [NSHC = 3-benzylbenzothiazolin-2-ylidene and 3- propylbenzothiazolin-2-ylidene] with triphenylphosphine, tricyclohexylphosphine and 2-diphenylphosphanyl-pyridine. All complexes have been fully characterized by 1H and 13C NMR spectroscopy, ESI mass spectrometry and elemental analysis. The X-ray crystal structures of complexes 3-8 are reported. The complexes exhibit moderate to good catalytic activity in the Suzuki-Miyaura coupling reaction of aryl bromides and chlorides. © The Royal Society of Chemistry 2008.
Source Title: Dalton Transactions
URI: http://scholarbank.nus.edu.sg/handle/10635/94488
ISSN: 14779226
DOI: 10.1039/b713152f
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