One-pot oxidation and protonation of a bridging sulfide and rare crystallographic evidence of a coordinated [SO] complex in [Pt 2(μ-S2O2H)(PPh3) 4]+

Please use this identifier to cite or link to this item: https://doi.org/10.1039/b902625h

Title:	One-pot oxidation and protonation of a bridging sulfide and rare crystallographic evidence of a coordinated [SO] complex in [Pt 2(μ-S2O2H)(PPh3) 4]+
Authors:	Li, J. Koh, L.L. Hor, T.S.A.
Issue Date:	2009
Citation:	Li, J., Koh, L.L., Hor, T.S.A. (2009). One-pot oxidation and protonation of a bridging sulfide and rare crystallographic evidence of a coordinated [SO] complex in [Pt 2(μ-S2O2H)(PPh3) 4]+. Chemical Communications (23) : 3416-3418. ScholarBank@NUS Repository. https://doi.org/10.1039/b902625h
Abstract:	One-pot oxidation and protonation of the sulfide bridging complex [Pt 2(μ-S)2(PPh3)4] can be promoted by lanthanide or scandium compounds, leading to the isolation of [Pt 2(μ-S2O2H)(PPh3) 4]+; crystallographic elucidation confirmed sulfide mono-oxygenation without S-S bonding to give formally [SO]2- in the form of an [SOHOS]3- overhead bridge. © 2009 The Royal Society of Chemistry.
Source Title:	Chemical Communications
URI:	http://scholarbank.nus.edu.sg/handle/10635/94422
ISSN:	13597345
DOI:	10.1039/b902625h
Appears in Collections:	Staff Publications

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