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|Title:||One-pot oxidation and protonation of a bridging sulfide and rare crystallographic evidence of a coordinated [SO] complex in [Pt 2(μ-S2O2H)(PPh3) 4]+|
|Citation:||Li, J., Koh, L.L., Hor, T.S.A. (2009). One-pot oxidation and protonation of a bridging sulfide and rare crystallographic evidence of a coordinated [SO] complex in [Pt 2(μ-S2O2H)(PPh3) 4]+. Chemical Communications (23) : 3416-3418. ScholarBank@NUS Repository. https://doi.org/10.1039/b902625h|
|Abstract:||One-pot oxidation and protonation of the sulfide bridging complex [Pt 2(μ-S)2(PPh3)4] can be promoted by lanthanide or scandium compounds, leading to the isolation of [Pt 2(μ-S2O2H)(PPh3) 4]+; crystallographic elucidation confirmed sulfide mono-oxygenation without S-S bonding to give formally [SO]2- in the form of an [SOHOS]3- overhead bridge. © 2009 The Royal Society of Chemistry.|
|Source Title:||Chemical Communications|
|Appears in Collections:||Staff Publications|
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