Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/94295
Title: Molecular adducts of diorganotin dichloride with N-(2-oxidoarylideneaminoacidato) diorganotin (IV) complexes. Crystal structure of [Ph2Sn(2-OC10H6CH=NCH2 COO)]SnPh2Cl2
Authors: Khoo, L.E.
Xu, Y.
Goh, N.K.
Chia, L.S.
Koh, L.L. 
Keywords: Diorganotin(IV) complexes
Spectroscopic studies
X-ray structure
Issue Date: 1997
Citation: Khoo, L.E.,Xu, Y.,Goh, N.K.,Chia, L.S.,Koh, L.L. (1997). Molecular adducts of diorganotin dichloride with N-(2-oxidoarylideneaminoacidato) diorganotin (IV) complexes. Crystal structure of [Ph2Sn(2-OC10H6CH=NCH2 COO)]SnPh2Cl2. Polyhedron 16 (4) : 573-576. ScholarBank@NUS Repository.
Abstract: Three new dinuclear tin complexes, [Me2Sn(2-OC6H4CH=NCH{Pr i}COO)]SnMe2Cl2 (1), [Me2Sn(2-OC10H6CH=NCH2COO)]SnMe 2Cl2 (2) and [Ph2Sn(2-OC10H6CH=NCH2COO)]SnPh 2Cl2 (3), were prepared and characterized by spectroscopic studies and elemental analyses as a 1 : 1 adduct between diorganotin dichloride (acceptor) and bicycloazastannoxide (donor). A full X-ray crystal structure analysis was performed on 3 and the results confirmed that the donor and the acceptor moieties of 3 are bonded with an Sn - O bond distance of 2.307 Å. Copyright © 1996 Elsevier Science Ltd.
Source Title: Polyhedron
URI: http://scholarbank.nus.edu.sg/handle/10635/94295
ISSN: 02775387
Appears in Collections:Staff Publications

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