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| Title: | Molecular adducts of diorganotin dichloride with N-(2-oxidoarylideneaminoacidato) diorganotin (IV) complexes. Crystal structure of [Ph2Sn(2-OC10H6CH=NCH2 COO)]SnPh2Cl2 | Authors: | Khoo, L.E. Xu, Y. Goh, N.K. Chia, L.S. Koh, L.L. |
Keywords: | Diorganotin(IV) complexes Spectroscopic studies X-ray structure |
Issue Date: | 1997 | Citation: | Khoo, L.E.,Xu, Y.,Goh, N.K.,Chia, L.S.,Koh, L.L. (1997). Molecular adducts of diorganotin dichloride with N-(2-oxidoarylideneaminoacidato) diorganotin (IV) complexes. Crystal structure of [Ph2Sn(2-OC10H6CH=NCH2 COO)]SnPh2Cl2. Polyhedron 16 (4) : 573-576. ScholarBank@NUS Repository. | Abstract: | Three new dinuclear tin complexes, [Me2Sn(2-OC6H4CH=NCH{Pr i}COO)]SnMe2Cl2 (1), [Me2Sn(2-OC10H6CH=NCH2COO)]SnMe 2Cl2 (2) and [Ph2Sn(2-OC10H6CH=NCH2COO)]SnPh 2Cl2 (3), were prepared and characterized by spectroscopic studies and elemental analyses as a 1 : 1 adduct between diorganotin dichloride (acceptor) and bicycloazastannoxide (donor). A full X-ray crystal structure analysis was performed on 3 and the results confirmed that the donor and the acceptor moieties of 3 are bonded with an Sn - O bond distance of 2.307 Å. Copyright © 1996 Elsevier Science Ltd. | Source Title: | Polyhedron | URI: | http://scholarbank.nus.edu.sg/handle/10635/94295 | ISSN: | 02775387 |
| Appears in Collections: | Staff Publications |
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