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https://doi.org/10.1039/c2ob25888a
| Title: | Locking high energy 1D chain of dichloromethane molecules containing abnormally short Cl⋯Cl contacts of 2.524 Å inside organic crystals | Authors: | Zhou, F. Fu, H. Ong, W.Q. Ye, R. Yuan, W. Lu, Y.-J. Huo, Y.-P. Zhang, K. Su, H. Zeng, H. |
Issue Date: | 7-Aug-2012 | Citation: | Zhou, F., Fu, H., Ong, W.Q., Ye, R., Yuan, W., Lu, Y.-J., Huo, Y.-P., Zhang, K., Su, H., Zeng, H. (2012-08-07). Locking high energy 1D chain of dichloromethane molecules containing abnormally short Cl⋯Cl contacts of 2.524 Å inside organic crystals. Organic and Biomolecular Chemistry 10 (29) : 5525-5528. ScholarBank@NUS Repository. https://doi.org/10.1039/c2ob25888a | Abstract: | 1D helical channels can be created by "sticky" end-mediated formation of 1D helical stacks composed of short cavity-containing helices and are able to host 1D chains of dichloromethane molecules containing extraordinarily short intermolecular Cl⋯Cl contacts of 2.524 Å in length that computationally destabilize the host-guest complex by 14.94 kcal mol-1. © 2012 The Royal Society of Chemistry. | Source Title: | Organic and Biomolecular Chemistry | URI: | http://scholarbank.nus.edu.sg/handle/10635/94166 | ISSN: | 14770520 | DOI: | 10.1039/c2ob25888a |
| Appears in Collections: | Staff Publications |
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