Locking high energy 1D chain of dichloromethane molecules containing abnormally short Cl⋯Cl contacts of 2.524 Å inside organic crystals
Zhou, F. Fu, H. Ong, W.Q. Ye, R. Yuan, W. Lu, Y.-J. Huo, Y.-P. Zhang, K. Su, H. Zeng, H.
Zhou, F.
Fu, H.
Ong, W.Q.
Ye, R.
Yuan, W.
Lu, Y.-J.
Huo, Y.-P.
Zhang, K.
Su, H.
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Abstract
1D helical channels can be created by "sticky" end-mediated formation of 1D helical stacks composed of short cavity-containing helices and are able to host 1D chains of dichloromethane molecules containing extraordinarily short intermolecular Cl⋯Cl contacts of 2.524 Å in length that computationally destabilize the host-guest complex by 14.94 kcal mol-1. © 2012 The Royal Society of Chemistry.
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Source Title
Organic and Biomolecular Chemistry
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Date
2012-08-07
DOI
10.1039/c2ob25888a
Type
Article