Please use this identifier to cite or link to this item: https://doi.org/10.1039/c2ob25888a
Title: Locking high energy 1D chain of dichloromethane molecules containing abnormally short Cl⋯Cl contacts of 2.524 Å inside organic crystals
Authors: Zhou, F.
Fu, H.
Ong, W.Q.
Ye, R.
Yuan, W.
Lu, Y.-J.
Huo, Y.-P.
Zhang, K.
Su, H.
Zeng, H. 
Issue Date: 7-Aug-2012
Citation: Zhou, F., Fu, H., Ong, W.Q., Ye, R., Yuan, W., Lu, Y.-J., Huo, Y.-P., Zhang, K., Su, H., Zeng, H. (2012-08-07). Locking high energy 1D chain of dichloromethane molecules containing abnormally short Cl⋯Cl contacts of 2.524 Å inside organic crystals. Organic and Biomolecular Chemistry 10 (29) : 5525-5528. ScholarBank@NUS Repository. https://doi.org/10.1039/c2ob25888a
Abstract: 1D helical channels can be created by "sticky" end-mediated formation of 1D helical stacks composed of short cavity-containing helices and are able to host 1D chains of dichloromethane molecules containing extraordinarily short intermolecular Cl⋯Cl contacts of 2.524 Å in length that computationally destabilize the host-guest complex by 14.94 kcal mol-1. © 2012 The Royal Society of Chemistry.
Source Title: Organic and Biomolecular Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/94166
ISSN: 14770520
DOI: 10.1039/c2ob25888a
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