Please use this identifier to cite or link to this item:
|Title:||Interconversion of a monomer and two coordination polymers of a copper(II) - Reduced schiff base ligand - 1,10-phenanthroline complex based on hydrogen- and coordinative-bonding||Authors:||Yang, C.T.
|Issue Date:||5-Nov-2001||Citation:||Yang, C.T., Moubaraki, B., Murray, K.S., Ranford, J.D., Vittal, J.J. (2001-11-05). Interconversion of a monomer and two coordination polymers of a copper(II) - Reduced schiff base ligand - 1,10-phenanthroline complex based on hydrogen- and coordinative-bonding. Inorganic Chemistry 40 (23) : 5934-5941. ScholarBank@NUS Repository. https://doi.org/10.1021/ic010479b||Abstract:||Two compounds, [Cu3(Sbal)2(phen)(H2O)2](ClO 4)2·3H2O (1) and [Cu(H2Sbal)2(phen)](ClO4)2 (2), were isolated in successive steps from the reaction mixture containing Cu(ClO4)2·6H2O, 1,10-phenanthroline, N-(2-hydroxybenzyl)-β-alanine (H2Sbal), and LiOH in the ratio of 1:1:1:1. When the ratio of the base was doubled, the neutral monomer [Cu(Sbal)(phen)]·2H2O (3) was obtained. The cation in 1 exists as a one-dimensional polymer in the solid state, while weak O - H··O hydrogen bonds in the cation of 2 generate ΔΛΔ||Source Title:||Inorganic Chemistry||URI:||http://scholarbank.nus.edu.sg/handle/10635/94072||ISSN:||00201669||DOI:||10.1021/ic010479b|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.