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|Title:||Interconversion of a monomer and two coordination polymers of a copper(II) - Reduced schiff base ligand - 1,10-phenanthroline complex based on hydrogen- and coordinative-bonding|
|Authors:||Yang, C.T. |
|Citation:||Yang, C.T., Moubaraki, B., Murray, K.S., Ranford, J.D., Vittal, J.J. (2001-11-05). Interconversion of a monomer and two coordination polymers of a copper(II) - Reduced schiff base ligand - 1,10-phenanthroline complex based on hydrogen- and coordinative-bonding. Inorganic Chemistry 40 (23) : 5934-5941. ScholarBank@NUS Repository. https://doi.org/10.1021/ic010479b|
|Abstract:||Two compounds, [Cu3(Sbal)2(phen)(H2O)2](ClO 4)2·3H2O (1) and [Cu(H2Sbal)2(phen)](ClO4)2 (2), were isolated in successive steps from the reaction mixture containing Cu(ClO4)2·6H2O, 1,10-phenanthroline, N-(2-hydroxybenzyl)-β-alanine (H2Sbal), and LiOH in the ratio of 1:1:1:1. When the ratio of the base was doubled, the neutral monomer [Cu(Sbal)(phen)]·2H2O (3) was obtained. The cation in 1 exists as a one-dimensional polymer in the solid state, while weak O - H··O hydrogen bonds in the cation of 2 generate ΔΛΔ|
|Source Title:||Inorganic Chemistry|
|Appears in Collections:||Staff Publications|
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