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|Title:||Hydrogen-bonded copper(II) and nickel(II) complexes and coordination polymeric structures containing reduced Schiff base ligands||Authors:||Sreenivasulu, B.
Hydrogen-bonded supramolecular networks
Reduced Schiff base
|Issue Date:||1-Jun-2009||Citation:||Sreenivasulu, B., Vittal, J.J. (2009-06-01). Hydrogen-bonded copper(II) and nickel(II) complexes and coordination polymeric structures containing reduced Schiff base ligands. Inorganica Chimica Acta 362 (8) : 2735-2743. ScholarBank@NUS Repository. https://doi.org/10.1016/j.ica.2008.12.018||Abstract:||Complexes [Cu(HSas)(H2O)] · 2H2O (H3Sas = N-(2-hydroxybenzyl)-l-aspartic acid) (1), [Cu(HMeSglu)(H2O)] · 2H2O (H3MeSglu = (N-(2-hydroxy-5-methylbenzyl)-l-glutamic acid) (2), [Cu2(Smet)2] (H2Smet = (N-(2-hydroxybenzyl)-l-methionine) (3), [Ni(HSas)(H2O)] (4), [Ni2(Smet)2(H2O)2] (5), and [Ni(HSapg)2] (H2Sapg = (N-(2-hydroxybenzyl)-l-aspargine) (6) have been synthesized and characterized by chemical and spectroscopic methods. Structural determination by single crystal X-ray diffraction studies revealed 1D coordination polymeric structures in 2 and 4, and hydrogen-bonded network structure in 5 and 6. In contrast to previously reported coordination compounds with similar ligands, the phenol remains protonated and bonded to the metal ions in 2 and 4, and also probably in 1. However, the phenolic group is non-bonded in 6. © 2009 Elsevier B.V. All rights reserved.||Source Title:||Inorganica Chimica Acta||URI:||http://scholarbank.nus.edu.sg/handle/10635/93989||ISSN:||00201693||DOI:||10.1016/j.ica.2008.12.018|
|Appears in Collections:||Staff Publications|
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