Please use this identifier to cite or link to this item:
https://doi.org/10.1016/j.ica.2008.12.018
DC Field | Value | |
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dc.title | Hydrogen-bonded copper(II) and nickel(II) complexes and coordination polymeric structures containing reduced Schiff base ligands | |
dc.contributor.author | Sreenivasulu, B. | |
dc.contributor.author | Vittal, J.J. | |
dc.date.accessioned | 2014-10-16T08:30:48Z | |
dc.date.available | 2014-10-16T08:30:48Z | |
dc.date.issued | 2009-06-01 | |
dc.identifier.citation | Sreenivasulu, B., Vittal, J.J. (2009-06-01). Hydrogen-bonded copper(II) and nickel(II) complexes and coordination polymeric structures containing reduced Schiff base ligands. Inorganica Chimica Acta 362 (8) : 2735-2743. ScholarBank@NUS Repository. https://doi.org/10.1016/j.ica.2008.12.018 | |
dc.identifier.issn | 00201693 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/93989 | |
dc.description.abstract | Complexes [Cu(HSas)(H2O)] · 2H2O (H3Sas = N-(2-hydroxybenzyl)-l-aspartic acid) (1), [Cu(HMeSglu)(H2O)] · 2H2O (H3MeSglu = (N-(2-hydroxy-5-methylbenzyl)-l-glutamic acid) (2), [Cu2(Smet)2] (H2Smet = (N-(2-hydroxybenzyl)-l-methionine) (3), [Ni(HSas)(H2O)] (4), [Ni2(Smet)2(H2O)2] (5), and [Ni(HSapg)2] (H2Sapg = (N-(2-hydroxybenzyl)-l-aspargine) (6) have been synthesized and characterized by chemical and spectroscopic methods. Structural determination by single crystal X-ray diffraction studies revealed 1D coordination polymeric structures in 2 and 4, and hydrogen-bonded network structure in 5 and 6. In contrast to previously reported coordination compounds with similar ligands, the phenol remains protonated and bonded to the metal ions in 2 and 4, and also probably in 1. However, the phenolic group is non-bonded in 6. © 2009 Elsevier B.V. All rights reserved. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.ica.2008.12.018 | |
dc.source | Scopus | |
dc.subject | Coordination polymers | |
dc.subject | Copper(II) complex | |
dc.subject | Hydrogen-bonded supramolecular networks | |
dc.subject | Ni(II) complex | |
dc.subject | Reduced Schiff base | |
dc.subject | Tridentate ligand | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.doi | 10.1016/j.ica.2008.12.018 | |
dc.description.sourcetitle | Inorganica Chimica Acta | |
dc.description.volume | 362 | |
dc.description.issue | 8 | |
dc.description.page | 2735-2743 | |
dc.description.coden | ICHAA | |
dc.identifier.isiut | 000265509200031 | |
Appears in Collections: | Staff Publications |
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