Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.ica.2008.12.018
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dc.titleHydrogen-bonded copper(II) and nickel(II) complexes and coordination polymeric structures containing reduced Schiff base ligands
dc.contributor.authorSreenivasulu, B.
dc.contributor.authorVittal, J.J.
dc.date.accessioned2014-10-16T08:30:48Z
dc.date.available2014-10-16T08:30:48Z
dc.date.issued2009-06-01
dc.identifier.citationSreenivasulu, B., Vittal, J.J. (2009-06-01). Hydrogen-bonded copper(II) and nickel(II) complexes and coordination polymeric structures containing reduced Schiff base ligands. Inorganica Chimica Acta 362 (8) : 2735-2743. ScholarBank@NUS Repository. https://doi.org/10.1016/j.ica.2008.12.018
dc.identifier.issn00201693
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/93989
dc.description.abstractComplexes [Cu(HSas)(H2O)] · 2H2O (H3Sas = N-(2-hydroxybenzyl)-l-aspartic acid) (1), [Cu(HMeSglu)(H2O)] · 2H2O (H3MeSglu = (N-(2-hydroxy-5-methylbenzyl)-l-glutamic acid) (2), [Cu2(Smet)2] (H2Smet = (N-(2-hydroxybenzyl)-l-methionine) (3), [Ni(HSas)(H2O)] (4), [Ni2(Smet)2(H2O)2] (5), and [Ni(HSapg)2] (H2Sapg = (N-(2-hydroxybenzyl)-l-aspargine) (6) have been synthesized and characterized by chemical and spectroscopic methods. Structural determination by single crystal X-ray diffraction studies revealed 1D coordination polymeric structures in 2 and 4, and hydrogen-bonded network structure in 5 and 6. In contrast to previously reported coordination compounds with similar ligands, the phenol remains protonated and bonded to the metal ions in 2 and 4, and also probably in 1. However, the phenolic group is non-bonded in 6. © 2009 Elsevier B.V. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.ica.2008.12.018
dc.sourceScopus
dc.subjectCoordination polymers
dc.subjectCopper(II) complex
dc.subjectHydrogen-bonded supramolecular networks
dc.subjectNi(II) complex
dc.subjectReduced Schiff base
dc.subjectTridentate ligand
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1016/j.ica.2008.12.018
dc.description.sourcetitleInorganica Chimica Acta
dc.description.volume362
dc.description.issue8
dc.description.page2735-2743
dc.description.codenICHAA
dc.identifier.isiut000265509200031
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