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| Title: | Formation of novel delocalised diphosphazene upon complexation-the preparation and X-ray structure of Os3(CO)10[(CF3)2PNPPh3]2 | Authors: | Ang, H.G. Cai, Y.M. Kwik, W.L. Morrison, E.C. Tocher, D.A. |
Issue Date: | 19-Feb-1991 | Citation: | Ang, H.G.,Cai, Y.M.,Kwik, W.L.,Morrison, E.C.,Tocher, D.A. (1991-02-19). Formation of novel delocalised diphosphazene upon complexation-the preparation and X-ray structure of Os3(CO)10[(CF3)2PNPPh3]2. Journal of Organometallic Chemistry 403 (3) : 383-385. ScholarBank@NUS Repository. | Abstract: | The compound Os3(C)10[(CF3)2PNPPh3]2 obtained from the reaction of Os3(CO)10(CH3CN)2 with (CF3)2P-NPPh3, has been characterized by X-ray crystallography. The osmium atoms from an approximate isoceles triangle. Both diphosphazene ligands which assume equatorial sites, contain unusually short PN bonds, from PNP to PNP upon coordination to osmium metals. © 1991. | Source Title: | Journal of Organometallic Chemistry | URI: | http://scholarbank.nus.edu.sg/handle/10635/93851 | ISSN: | 0022328X |
| Appears in Collections: | Staff Publications |
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