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| Title: | Facile complexation of 1,1′-bis(diphenylphosphino) ruthenocene (dppr) to ruthenium(II) - Simple entry to stable bimetallic ruthenoruthenocenyl system | Authors: | Wei, B. Li, S. Lee, H.K. Hor, T.S.A. |
Keywords: | Carbonyl Group 8 Heterobimetallics Phosphine Ruthenecene Ruthenium |
Issue Date: | 11-Jan-1997 | Citation: | Wei, B.,Li, S.,Lee, H.K.,Hor, T.S.A. (1997-01-11). Facile complexation of 1,1′-bis(diphenylphosphino) ruthenocene (dppr) to ruthenium(II) - Simple entry to stable bimetallic ruthenoruthenocenyl system. Journal of Organometallic Chemistry 527 (1-2) : 133-136. ScholarBank@NUS Repository. | Abstract: | Phosphine exchange occurs rapidly between RuCl2(PPh3)n (n = 3, 4) and Ru(C5H4PPh2)2 (dppr) at room temperature to give RuCl2(dppr)(PPh3), 1. Triphenylphosphine is more substitutionally labile than dppr in 1; selective phosphine substitution of 1 with CO and CH3CN gives [RuCl2(CO)(dppr)] and two geometric isomers of [RuCl2(NCCH3)2(dppr)] respectively. | Source Title: | Journal of Organometallic Chemistry | URI: | http://scholarbank.nus.edu.sg/handle/10635/93792 | ISSN: | 0022328X |
| Appears in Collections: | Staff Publications |
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