Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/93792
Title: Facile complexation of 1,1′-bis(diphenylphosphino) ruthenocene (dppr) to ruthenium(II) - Simple entry to stable bimetallic ruthenoruthenocenyl system
Authors: Wei, B.
Li, S. 
Lee, H.K. 
Hor, T.S.A. 
Keywords: Carbonyl
Group 8
Heterobimetallics
Phosphine
Ruthenecene
Ruthenium
Issue Date: 11-Jan-1997
Source: Wei, B.,Li, S.,Lee, H.K.,Hor, T.S.A. (1997-01-11). Facile complexation of 1,1′-bis(diphenylphosphino) ruthenocene (dppr) to ruthenium(II) - Simple entry to stable bimetallic ruthenoruthenocenyl system. Journal of Organometallic Chemistry 527 (1-2) : 133-136. ScholarBank@NUS Repository.
Abstract: Phosphine exchange occurs rapidly between RuCl2(PPh3)n (n = 3, 4) and Ru(C5H4PPh2)2 (dppr) at room temperature to give RuCl2(dppr)(PPh3), 1. Triphenylphosphine is more substitutionally labile than dppr in 1; selective phosphine substitution of 1 with CO and CH3CN gives [RuCl2(CO)(dppr)] and two geometric isomers of [RuCl2(NCCH3)2(dppr)] respectively.
Source Title: Journal of Organometallic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/93792
ISSN: 0022328X
Appears in Collections:Staff Publications

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