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|Title:||Facile complexation of 1,1′-bis(diphenylphosphino) ruthenocene (dppr) to ruthenium(II) - Simple entry to stable bimetallic ruthenoruthenocenyl system|
|Source:||Wei, B.,Li, S.,Lee, H.K.,Hor, T.S.A. (1997-01-11). Facile complexation of 1,1′-bis(diphenylphosphino) ruthenocene (dppr) to ruthenium(II) - Simple entry to stable bimetallic ruthenoruthenocenyl system. Journal of Organometallic Chemistry 527 (1-2) : 133-136. ScholarBank@NUS Repository.|
|Abstract:||Phosphine exchange occurs rapidly between RuCl2(PPh3)n (n = 3, 4) and Ru(C5H4PPh2)2 (dppr) at room temperature to give RuCl2(dppr)(PPh3), 1. Triphenylphosphine is more substitutionally labile than dppr in 1; selective phosphine substitution of 1 with CO and CH3CN gives [RuCl2(CO)(dppr)] and two geometric isomers of [RuCl2(NCCH3)2(dppr)] respectively.|
|Source Title:||Journal of Organometallic Chemistry|
|Appears in Collections:||Staff Publications|
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