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https://doi.org/10.1002/anie.200502532
| Title: | Ethylene oligomerization at coordinatively and electronically unsaturated low-valent nickel | Authors: | Weng, Z. Teo, S. Lip, L.K. Hor, T.S.A. |
Keywords: | Coordination modes Homogeneous catalysis N,P ligands Nickel Oligomerization |
Issue Date: | 25-Nov-2005 | Citation: | Weng, Z., Teo, S., Lip, L.K., Hor, T.S.A. (2005-11-25). Ethylene oligomerization at coordinatively and electronically unsaturated low-valent nickel. Angewandte Chemie - International Edition 44 (46) : 7560-7564. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.200502532 | Abstract: | (Chemical Equation Presented) Three modes: An iminoferrocenylphosphane ligand stabilizes low-coordinate and low-valent nickel in [{[η-C 5H4CH=N-(C6H5)]Fe[η-C 5H4P(tBu)2]-N,P}NiICl] (see figure) and similar complexes. The coordination environment is hemilabile as exemplified by three different coordination modes: P,N(σ)-chelate, P,CN(π)-chelate, and P unidentate. These complexes are catalytically active towards ethylene oligomerization. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA. | Source Title: | Angewandte Chemie - International Edition | URI: | http://scholarbank.nus.edu.sg/handle/10635/93771 | ISSN: | 14337851 | DOI: | 10.1002/anie.200502532 |
| Appears in Collections: | Staff Publications |
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